Adenosine 5′-[(S)α-thio-γ-benzyl]triphosphate on treatment with cyanogen bromide in [18O]water gives [α-18O]- and [γ-18O]-adenosine 5′-[γ-benzyl]triphosphate in about equal amounts, the [α-18O] material being formed with retention of configuration at phosphorus providing support for a mechanism involving participation by the γ-phosphate group.
G. Lowe and G. Semple, J. Chem. Soc., Chem. Commun., 1988, 377 DOI: 10.1039/C39880000377
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