Restricted rotation of the arene ring in complexes of the type (arene)M(CO)3-x(SiCl3)x(M = Re, x= 1; M = Ru, Os, x= 2) appears to occur when the ring is prevented from tilting by the presence of two bulky groups on both the arene ring and the transition metal.
X. Hu, J. Duchowski and R. K. Pomeroy, J. Chem. Soc., Chem. Commun., 1988, 362 DOI: 10.1039/C39880000362
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