The cyano group in [B10H13CN]2– occupies an endo-position with respect to the cage in both solution (n.m.r.) and solid (X-ray crystallography) states, indicating a general pathway for the formation of heteroboranes.
K. Baše, N. W. Alcock, O. W. Howarth, H. R. Powell, A. T. Harrison and M. G. H. Wallbridge, J. Chem. Soc., Chem. Commun., 1988, 341 DOI: 10.1039/C39880000341
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