Thermolysis of 1-(N-acetyl-N-aryl)amino-2,4,6-triphenylpyridinium tetrafluoroborates provides a new and synthetically useful source of arylnitrenium ions under non-acidic conditions; a p-semidine-type byproduct is obtained from the phenylamino compound.
R. A. Abramovitch, K. Evertz, G. Huttner, H. H. Gibson and H. G. Weems, J. Chem. Soc., Chem. Commun., 1988, 325 DOI: 10.1039/C39880000325
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