The (triphos)Rh fragment [triphos = MeC(CH2PPh2)3] is able to form strong bonds with several reactive species (hydride, alkyl, carbon monoxide, alkenes), some reactions of which are highly specific; preliminary results on the hydrogenation and hydroformylation of hex-1-ene using (triphos)RhH(C2H4) as catalyst precursor are discussed.
C. Bianchini, A. Meli, M. Peruzzini, F. Vizza, Y. Fujiwara, T. Jintoku and H. Taniguchi, J. Chem. Soc., Chem. Commun., 1988, 299 DOI: 10.1039/C39880000299
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