In aqueous solutions of sodium dithionite, nitroso spin traps form stable nitroxide spin adducts RN(O·)SO3– as proven by their 17O hyperfine structure, rather than sulphur dioxide anion radical adducts, RN(O·)SO2–, as has been reported.
K. Stolze, D. R. Duling and R. P. Mason, J. Chem. Soc., Chem. Commun., 1988, 268 DOI: 10.1039/C39880000268
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