Acetylenedicarbaldehyde (1) is isolated in the pure state after acidolysis of its monoacetal (2) with an excess of formic acid followed by dehydration of residual HCO2H into CO with P2O5; under neutral conditions, (1) reacts with conjugated dienes as a dienophile only, in contrast to what occurs in acidic medium.
D. Stéphan, A. Gorgues, A. Belyasmine and A. Le Coq, J. Chem. Soc., Chem. Commun., 1988, 263 DOI: 10.1039/C39880000263
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...