A series of luminescent alkyl complexes of formula IrR(CO)L2(mnt), where mnt = maleonitriledithiolate, R = Me, Et, Pr, and CH2CN, and L is a triarylphosphine, have been characterized; photolysis of IrMe(CO)(PPh3)2(mnt) shows that Ir–Me bond homolysis is favoured strongly over CO photo-dissociation.
P. Bradley, C. E. Johnson and R. Eisenberg, J. Chem. Soc., Chem. Commun., 1988, 255 DOI: 10.1039/C39880000255
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