Synthesis and crystal structure of [(Ph3P)2N][HRu3(CO)9(PhNCO)], a ruthenium cluster with a phenyl isocyanate ligand
Abstract
The ruthenium cluster [PPN][HRu3(CO)9(PhNCO)]{[PPN]=(Ph3P)2N} has been synthesised by intramolecular nucleophilic attack on CO and characterised by X-ray structure determination.