Issue 3, 1988

Preparation of a penta-ammineruthenium(III) derivative of Chromatium vinosum HIPIP and the kinetics of intramolecular electron transfer

Abstract

The rate constant (∼20 °C) for intramolecular electron transfer from Ru(NH3)52+ attached at the Histidine-42 of HIPIP to the [4Fe–4S](oxidised) active site, distance 7.9 Å, is 18 s–1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 179-180

Preparation of a penta-ammineruthenium(III) derivative of Chromatium vinosum HIPIP and the kinetics of intramolecular electron transfer

M. P. Jackman, M. Lim, G. A. Salmon and A. G. Sykes, J. Chem. Soc., Chem. Commun., 1988, 179 DOI: 10.1039/C39880000179

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