H4Ru4(CO)8L4(L = PBu3n) catalyses selective transfer hydrogenation of α,β-unsaturated aldehydes to α,β-unsaturated alcohols; kinetic and deuterium labelling studies indicate involvement of cluster intermediates and no participation by the cluster hydrides.
S. Bhaduri and K. Sharma, J. Chem. Soc., Chem. Commun., 1988, 173 DOI: 10.1039/C39880000173
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