Issue 2, 1988

Generation of the 1,4-diphenylcyclohexane-1,4-diyl radical cation by CeIV-catalysed denitrogenation of the azoalkane 1,4-diphenyl-2,3-diazabicyclo[2.2.2]oct-2-ene and its reluctance to undergo Cope rearrangement

Abstract

It is experimentally confirmed that the radical cation of 1,4-diphenylcyclohexane-1,4-diyl does not isomerize thermally to the radical cation of 2,5-diphenylhexa-1,5-diene, but is instead quantitatively dehydrogenated to p-terphenyl.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 142-143

Generation of the 1,4-diphenylcyclohexane-1,4-diyl radical cation by CeIV-catalysed denitrogenation of the azoalkane 1,4-diphenyl-2,3-diazabicyclo[2.2.2]oct-2-ene and its reluctance to undergo Cope rearrangement

W. Adam, S. Grabowski, M. A. Miranda and M. Rübenacker, J. Chem. Soc., Chem. Commun., 1988, 142 DOI: 10.1039/C39880000142

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