Oxidation of sterically crowded sulphides containing a 2,4,6-tri-t-butylphenyl group or its Dewar benzene analogue affords unusually unstable sulphoxides which undergo ready heterolytic S–Cα cleavage to give indan derivatives and sulphenic acids.
R. Okazaki, T. Ishida and N. Inamoto, J. Chem. Soc., Chem. Commun., 1988, 40 DOI: 10.1039/C39880000040
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