Issue 1, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Unprecedented reactivity of vinylidene complexes with diazomethane: insertion of the methylene group into a C–H bond

Giambattista Consiglio,   Roger Schwab  and  Franco Morandini  

Abstract

[(η-C5H5)Ru{Ph2PCH(Me)CH(Me)PPh2}(C[double bond, length half m-dash]CHR)]PF6(R = Ph or But) react with diazomethane to give the corresponding methylvinylidene complexes [(η-C5H5)Ru{Ph2PCH(Me)CH(Me)PPh2}{C[double bond, length half m-dash]C(Me)R}]PF6; this novel type of reactivity suggests an alternative mechanism for the formation of branched hydrocarbons in the Fischer–Tropsch synthesis.

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Article information

DOI
https://doi.org/10.1039/C39880000025
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 25-26

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Unprecedented reactivity of vinylidene complexes with diazomethane: insertion of the methylene group into a C–H bond

G. Consiglio, R. Schwab and F. Morandini, J. Chem. Soc., Chem. Commun., 1988, 25 DOI: 10.1039/C39880000025

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