Equations are derived for the calculation of the solubility product, Ksp, of a sparingly soluble salt AmBn from e.m.f. measurements with an electrode responding to ion A before and after the addition of V ml of a standard solution of A to V0 ml of a saturated solution of AmBn. Ksp is expressed in terms of the e.m.f. shift, ΔE, and an independently determined slope factor.
D. Midgley, Analyst, 1988, 113, 1743 DOI: 10.1039/AN9881301743
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