Issue 8, 1987

Oxidation of thiones to sulphines (thione S-oxides) with N-sulphonyloxaziridines: synthetic and mechanistic aspects

Abstract

The kinetics of the two-step oxidation of diarylthiones by N-sulphonyloxaziridines to sulphines and then to ketones have been investigated and the results compared with those for reactions with perbenzoic acid. The synthetic utility of the oxaziridine and peracid oxidations has been compared for a few aliphatic thiones.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1987, 1113-1116

Oxidation of thiones to sulphines (thione S-oxides) with N-sulphonyloxaziridines: synthetic and mechanistic aspects

G. Maccagnani, A. Innocenti, P. Zani and A. Battaglia, J. Chem. Soc., Perkin Trans. 2, 1987, 1113 DOI: 10.1039/P29870001113

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