(S)- and (R)-[2-2H]isopentenyl pyrophosphates, which are useful precursors for stereochemical studies on the biosynthesis of isoprenoids, were chemically synthesized in five steps via(S)- and (R)-3-methyl-2,3-epoxybutan-1-ols starting with 3,3-dimethylallyl alcohol, in 18% and 15% overall yields, respectively.
T. Suga, S. Ohta and T. Ohmoto, J. Chem. Soc., Perkin Trans. 1, 1987, 2845 DOI: 10.1039/P19870002845
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