Issue 0, 1987

Allyl sulphide synthesis by phenylthio migration: relationship between stereochemistry of starting materials and regioselectivity of double bond formation

Abstract

Phenylthio migration to an alkyl migration terminus can be controlled to give mostly an allyl sulphide with a trisubstituted double bond and good E : Z selectivity but migration to a benzylic migration terminus is affected by stereochemistry: each diastereoisomer of the starting material preferentially forms one of two regioisomeric allylic sulphides.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 2579-2584

Allyl sulphide synthesis by phenylthio migration: relationship between stereochemistry of starting materials and regioselectivity of double bond formation

V. K. Aggarwal and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1987, 2579 DOI: 10.1039/P19870002579

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