Hydration of the 16-ene in the gibberellins is shown, by a combination of spectroscopic and X-ray crystallographic means, to lead to (16R)-alcohols. The hydrochloride of gibberellin A9 methyl ester possesses the same (16R)-stereochemistry.
K. M. Abouamer, J. R. Hanson and P. B. Hitchcock, J. Chem. Soc., Perkin Trans. 1, 1987, 1991 DOI: 10.1039/P19870001991
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