Optically active 3-substituted carboxylic acids and (S)-(–)-citronellol have been obtained by diastereoselective conjugate addition of Grignard reagents co-ordinated with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) to chiral amido alcohols derived from (S)-proline.
K. Soai, H. Machida and N. Yokota, J. Chem. Soc., Perkin Trans. 1, 1987, 1909 DOI: 10.1039/P19870001909
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