Issue 0, 1987

Metal-assisted reactions: part 19. Burst kinetics in heterogeneous catalytic transfer hydrogenolysis

Abstract

Arene formation by catalytic transfer hydrogenolysis of aryloxytetrazolyl ethers in the liquid-phase shows biphasic concentration-time curves which indicate rate-limiting dissociation of heterogeneous complexes between catalyst and one of the reaction products, a tetrazolone. A dependence of catalytic reaction rate on pH and following modifications made to the catalyst are reported also.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 1069-1076

Metal-assisted reactions: part 19. Burst kinetics in heterogeneous catalytic transfer hydrogenolysis

R. A. W. Johnstone and P. J. Price, J. Chem. Soc., Perkin Trans. 1, 1987, 1069 DOI: 10.1039/P19870001069

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