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Anisole yields both ortho- and meta-cycloadducts upon irradiation in the presence of 1,3-dioxole and 2,2-dimethyl-1,3-dioxole. The mode and the regio- and stereo-selectivities of these cycloadditions are rationalized on the basis of the exciplex–zwitterion mechanism.
J. Mattay, J. Runsink, J. A. Piccirilli, A. W. H. Jens and J. Cornelisse, J. Chem. Soc., Perkin Trans. 1, 1987, 15 DOI: 10.1039/P19870000015
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