Issue 8, 1987

Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2 ligands

Abstract

The reactions of cis-[M(C6F5)2(thf)2], trans-[M(C6F5)2(tht)2], and [M2(µ-Cl)2(C6F5)2(tht)2](M = Pd or Pt, thf = tetrahydrofuran, tht = tetrahydrothiophene) with dppm (Ph2PCH2PPh2) in molar ratios M : dppm = 1 : 1 and 1 : 2 have been studied. Pentafluorophenyl complexes containing dppm acting as endobidentate (chelate), unidentate, or exobidentate (bridging homo- or hetero-metal centres) have been obtained and characterized by i.r. and 31P n.m.r. spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 2077-2081

Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2 ligands

R. Usón, J. Forniés, P. Espinet, R. Navarro and C. Fortuño, J. Chem. Soc., Dalton Trans., 1987, 2077 DOI: 10.1039/DT9870002077

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