Issue 8, 1987
From the journal:

Journal of the Chemical Society, Dalton Transactions

Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2 ligands

Rafael Usón,   Juan Forniés,   Pablo Espinet,   Rafael Navarro  and  Consuelo Fortuño  

Abstract

The reactions of cis-[M(C6F5)2(thf)2], trans-[M(C6F5)2(tht)2], and [M2(µ-Cl)2(C6F5)2(tht)2](M = Pd or Pt, thf = tetrahydrofuran, tht = tetrahydrothiophene) with dppm (Ph2PCH2PPh2) in molar ratios M : dppm = 1 : 1 and 1 : 2 have been studied. Pentafluorophenyl complexes containing dppm acting as endobidentate (chelate), unidentate, or exobidentate (bridging homo- or hetero-metal centres) have been obtained and characterized by i.r. and 31P n.m.r. spectroscopy.

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Article information

DOI
https://doi.org/10.1039/DT9870002077
Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 2077-2081

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Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2 ligands

R. Usón, J. Forniés, P. Espinet, R. Navarro and C. Fortuño, J. Chem. Soc., Dalton Trans., 1987, 2077 DOI: 10.1039/DT9870002077

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