Alkoxy-bridged chromyl(VI) alkoxides, [CrO2(OR)2] and [CrO2Cl(OR)](R = CH2CCl3, CH2CF3, or CH2CH2Cl), have been synthesized. They react with oxygen- and nitrogen-donor ligands to form adducts. The alkoxides and their adducts have been characterized by elemental analyses, cryoscopic studies, i.r., 1H and 19F n.m.r., and mass spectra.
S. L. Chadha, V. Sharma and A. Sharma, J. Chem. Soc., Dalton Trans., 1987, 1253 DOI: 10.1039/DT9870001253
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