SCHEDULED MAINTENANCE:
Cyclopentadienyliron tellurophosphorane cations [Fe(C5H5)(CO)2(TePR3)]+(5; R = Me, Pri, But, NMe2, or morpholino) have been prepared by reaction of [Fe(C5H5)(CO)2(thf)]+(thf = C4H8O) with TePR3. The bonding properties of the Fe–Te–P fragment are discussed using n.m.r. data which indicate π bonding between the iron and tellurium atoms.
N. Kuhn and H. Schumann, J. Chem. Soc., Dalton Trans., 1987, 541 DOI: 10.1039/DT9870000541
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