The F + I2→ IF + I reaction has been studied in a crossed-beam experiment. The IF rovibrational distribution has been measured with the laser-induced fluorescence detection technique. Many new and important results concerning the energy disposal in this reaction are thus obtained. Moreover, a bimodal rotational distribution is observed in several vibrational levels: this phenomenon seems to be due to migratory collisions.
B. Girard, N. Billy, G. Gouédard and J. Vigué, Faraday Discuss. Chem. Soc., 1987, 84, 65 DOI: 10.1039/DC9878400065
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