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Issue 15, 1987
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Stereocontrolled route to 3-amino-2,3,6-trideoxy-hexopyranoses. K-10 Montmorillonite as a glycosidation reagent for acosaminide synthesis

Abstract

A stereoselective synthesis of methyl (or benzyl) 3-azido-2,3,6-trideoxy-α-L-arabino-hexopyranoside from di-O-acetyl-L-rhamnal is reported; it proceeds via addition of hydrazoic acid to a hex-2-enopyranose, followed by acetylation and glycosidation with the appropriate alcohol, in the presence of K-10 montmorillonite as catalyst.

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Article type: Paper
DOI: 10.1039/C39870001171
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 1171-1172

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    Stereocontrolled route to 3-amino-2,3,6-trideoxy-hexopyranoses. K-10 Montmorillonite as a glycosidation reagent for acosaminide synthesis

    J. Florent and C. Monneret, J. Chem. Soc., Chem. Commun., 1987, 0, 1171
    DOI: 10.1039/C39870001171

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