Issue 24, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Volumes of activation for kinetically labile organometallic complexes: solvent displacement from cis-[(C6H5Cl)(PPh2R)W(CO)4][R = Ph, (CH2)4CH[double bond, length as m-dash]CH2] in chlorobenzene solution

Hani H. Awad,   Gerard R. Dobson  and  Rudi van Eldik  

Abstract

Large, positive, and similar volumes of activation, indicative of dissociative desolvation mechanisms, have been observed for chlorobenzene displacement by pyridien and through chelate ring closure, respectively, from cis-[(C6H5Cl)(PPh2R)W(CO)4] complexes [R = Ph, (CH2)4C[double bond, length as m-dash]CH2] produced via pulsed laser flash photolysis.

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Article information

DOI
https://doi.org/10.1039/C39870001839
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1839-1841

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Volumes of activation for kinetically labile organometallic complexes: solvent displacement from cis-[(C6H5Cl)(PPh2R)W(CO)4][R = Ph, (CH2)4CH[double bond, length as m-dash]CH2] in chlorobenzene solution

H. H. Awad, G. R. Dobson and R. van Eldik, J. Chem. Soc., Chem. Commun., 1987, 1839 DOI: 10.1039/C39870001839

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