Unlike its metal-free precursor and NiII analogue, meso-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)- porphyrinatopalladium(II) undergoes very little aerial oxidation in basified dichloromethane, owing to metal-enforced planarity of the porphyrin macrocycle, as shown by crystal structure determinations of the two complexes.
A. J. Golder, L. R. Milgrom, K. B. Nolan and D. C. Povey, J. Chem. Soc., Chem. Commun., 1987, 1788 DOI: 10.1039/C39870001788
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