Reaction of silyl enol ethers (1a–f) with N-chlorosuccinimide afforded siloxycarbinyl cations which were trapped by nucleophiles (NaN3 and MeOH); subsequent rearrangement of the azido products (2a,b,d,e–N3) under reflux in decalin led to anilide derivatives (3a,b,d,e).
K. Ohkata, M. Mase and K. Akiba, J. Chem. Soc., Chem. Commun., 1987, 1727 DOI: 10.1039/C39870001727
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