On the nature of charge distribution in the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion. 13C n.m.r. vs. stability data

George Trimitsis; Fu-Tyan Lin; Richard Eaton; Samantha Jones; Milton Trimitsis; Scott Lane

doi:10.1039/C39870001704

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

On the nature of charge distribution in the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion. ¹³C n.m.r. vs. stability data

George Trimitsis, Fu-Tyan Lin, Richard Eaton, Samantha Jones, Milton Trimitsis and Scott Lane

Abstract

Whereas the ¹³C n.m.r. spectrum of the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion (1) displayed a number of features suggestive of long range π-interactions, its stability was found to be only slightly higher than that of its 6,7-dihydro analogue (4) thereby ruling out the possibility that homoaromaticity plays an important role in the stabilization of this species.

Download options Please wait...

Article information

DOI: https://doi.org/10.1039/C39870001704
Article type: Paper

Download Citation

J. Chem. Soc., Chem. Commun., 1987, 1704-1706

Permissions

Request permissions

On the nature of charge distribution in the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion. ¹³C n.m.r. vs. stability data

G. Trimitsis, F. Lin, R. Eaton, S. Jones, M. Trimitsis and S. Lane, J. Chem. Soc., Chem. Commun., 1987, 1704 DOI: 10.1039/C39870001704

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Fetching data from CrossRef.
This may take some time to load.

Journal of the Chemical Society, Chemical Communications

On the nature of charge distribution in the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion. ¹³C n.m.r. vs. stability data

Abstract

Article information

Download Citation

Permissions

On the nature of charge distribution in the 2,4-diphenylbicyclo[3.2.1]oct-6-en-3-one dianion. ¹³C n.m.r. vs. stability data

Search articles by author

Spotlight

Advertisements