The new reagent bis(trimethylsilyl)cyanamide reacts with S3N2Cl2 and (NSCl)3 to give [graphic omitted]·NCN and CClS3N5 in good yields; the crystal structures of both products have been determined.
A. J. Banister, W. Clegg, I. B. Gorrell, Z. V. Hauptman and R. W. H. Small, J. Chem. Soc., Chem. Commun., 1987, 1611 DOI: 10.1039/C39870001611
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