Issue 20, 1987

An efficient synthesis of chiral quaternary carbon centres with high optical purity via 1,3-chirality transfer

Abstract

An efficient synthesis of chiral quaternary carbon centres via Me2Cu(CN)Li2·BF3 or RCu(CN)Li·BF3(R ≠ Me) mediated 1,3-chirality transfer of α-alkyl-γ-mesyloxy-α,β-enoates is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1596-1598

An efficient synthesis of chiral quaternary carbon centres with high optical purity via 1,3-chirality transfer

T. Ibuka, M. Tanaka, S. Nishii and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1987, 1596 DOI: 10.1039/C39870001596

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