Complementary and high diastereoselection is readily achieved by changing the geometry of the double bond in the base-induced cyclization of acyclic unsaturated amine derivatives (2), leading to the stereodivergent synthesis of 2,3-disubstituted piperidines.
M. Hirama, T. Iwakuma and S. Itô, J. Chem. Soc., Chem. Commun., 1987, 1523 DOI: 10.1039/C39870001523
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