Dithioacetals react with Grignard reagents in the presence of a catalytic amount of [NiCl2(PPh3)2] to give the corresponding olefinic coupling products in good yields; a mechanism for the reaction is suggested.
Z. Ni and T. Luh, J. Chem. Soc., Chem. Commun., 1987, 1515 DOI: 10.1039/C39870001515
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