Issue 19, 1987

Reduction of the steric hindrance to conjugation in 3,4-disubstituted poly(thiophenes); cyclopenta[c]thiophene and thieno[c]thiophene as precursors of electrogenerated conducting polymers

Abstract

The cyclopenta[c]thiophene (1) and thieno[c]thiophene (2) have been synthesized and used as substrates for electropolymerization; steric hindrances is less in poly(1) than in poly(3,4-dialkylthiophenes), while attempts to electropolymerize (2) were unsuccessful.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1500-1502

Reduction of the steric hindrance to conjugation in 3,4-disubstituted poly(thiophenes); cyclopenta[c]thiophene and thieno[c]thiophene as precursors of electrogenerated conducting polymers

J. Roncali, F. Garnier, R. Garreau and M. Lemaire, J. Chem. Soc., Chem. Commun., 1987, 1500 DOI: 10.1039/C39870001500

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