2-(N-Nitrosomethylamino-oxy)ethyl ketones (3), obtained from solvolysis with sodium nitrite of N-methyl-4,5-dihyroisoxazolium methylsulphates (2), were converted into α,β-unsaturated ketones (4) by treatment with base or into β-hydroxy ketones (5) by treatment with carboxylic acids.
S. Kwiatkowski, J. Chem. Soc., Chem. Commun., 1987, 1496 DOI: 10.1039/C39870001496
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