Collisionally induced decomposition mass spectrometry has shown that during the gas phase reaction of CH5+ with fluorobenzene at temperatures <300 K, a proton transfers preferentially to the F atom even though its proton affinity is ca. 180 kJ mol–1 less than the ring.
R. Mason, D. Milton and F. Harris, J. Chem. Soc., Chem. Commun., 1987, 1453 DOI: 10.1039/C39870001453
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