Issue 19, 1987

Stereospecific synthesis of carbocyclic analogue of oxazinomycin by retrograde aldol C–C bond fission under reductive conditions

Abstract

The Diels–Alder adduct prepared from cyclopentadiene and methyl (E)-3-acetoxy-2-cyanoacrylate (a newly synthesized dienophile) can be converted stereospecifically into the title compound using a retrograde aldol reaction under reductive conditions as a key step.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1422-1423

Stereospecific synthesis of carbocyclic analogue of oxazinomycin by retrograde aldol C–C bond fission under reductive conditions

N. Katagiri, M. Tomura, T. Haneda and C. Kaneko, J. Chem. Soc., Chem. Commun., 1987, 1422 DOI: 10.1039/C39870001422

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