Vinylphosphane—how effective is π-donation from phosphorus lone pairs?
Abstract
Ab initio calculations show that vinylphosphane prefers a ground state geometry with the phosphorus lone pair perpendicular to the alkene π-system.
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J. Chem. Soc., Chem. Commun., 1987, 1399-1401
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Vinylphosphane—how effective is π-donation from phosphorus lone pairs?
C. Schade and P. von Ragué Schleyer, J. Chem. Soc., Chem. Commun., 1987, 1399 DOI: 10.1039/C39870001399
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