Issue 18, 1987

Oxidation of N-aminoquinazolones in the presence of alkenes: evidence against involvement of N-nitrenes

Abstract

Solutions of 2-ethyl-3-acetoxyamino-4(3H)-quinazolone (6) have been obtained by oxidation of the corresponding 3-aminoquinazolone (4) with lead tetra-acetate at –20 °C; (6) brings about aziridination of alkenes by a mechanism that does not involve N-nitrene or N-nitrenium ion intermediates.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1362-1363

Oxidation of N-aminoquinazolones in the presence of alkenes: evidence against involvement of N-nitrenes

R. S. Atkinson and B. J. Kelly, J. Chem. Soc., Chem. Commun., 1987, 1362 DOI: 10.1039/C39870001362

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