Co-ordination of the acyl oxygen atom in a di-iron µ2-η2-(C,C)-ketene complex, Fp–CH2CO–Fp [Fp =(η5-C5H5)Fe(CO)2] to Lewis acidic organometallic centres produces cationic trinuclear µ3-η3-(C,C,O)-ketene complexes, the two metal components of which exchange with each other via an intramolecular process.
M. Akita, T. Kawahara and Y. Moro-oka, J. Chem. Soc., Chem. Commun., 1987, 1356 DOI: 10.1039/C39870001356
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