Issue 18, 1987

Evidence for generation of the unsaturated sila-acetate species Me(O)Si[double bond, length half m-dash]O by dissociation of the silanediolate dianion m-ClC6H4CH2SiMe(O)2

Abstract

Kinetic studies indicate that in the cleavage of m-ClC6H4CH2SiMe(OH)2 by NaOH in Me2SO–H2O there is a major contribution by unimolecular dissociation of the dianion m-ClC6H4CH2SiMe(O)2 to give the acetate ion analogue Me(O)Si[double bond, length half m-dash]O.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1337-1338

Evidence for generation of the unsaturated sila-acetate species Me(O)Si[double bond, length half m-dash]O by dissociation of the silanediolate dianion m-ClC6H4CH2SiMe(O)2

J. Chmielecka, J. Chojnowski, C. Eaborn and W. A. Stańcyzk, J. Chem. Soc., Chem. Commun., 1987, 1337 DOI: 10.1039/C39870001337

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