The first bicyclo[2.2.0]hexasilane, decaisopropylhexasilabicyclo[2.2.0]hexane was synthesized by the co-condensation of 1,1,2,2-tetrachlorodi-isopropyldisilane and 1,2-dichlorotetraisopropyldisilane with lithium in tetrahydrofuran.
H. Matsumoto, H. Miyamoto, N. Kojima and Y. Nagai, J. Chem. Soc., Chem. Commun., 1987, 1316 DOI: 10.1039/C39870001316
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