An easy procedure for the synthesis of electron-poor 2-aza-1,3-dienes from silylimines is described; the ability of these azadienes to undergo cycloaddition to electron-rich alkenes is demonstrated for the first time.
J. Barluenga, M. Tomás, A. Ballesteros and V. Gotor, J. Chem. Soc., Chem. Commun., 1987, 1195 DOI: 10.1039/C39870001195
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