The vapour pressure of a racemic mixture forming a conglomerate is exactly twice that of the pure enantiomers; that of a crystalline racemic compound may be higher or lower than that of the enantiomers, and depends chiefly on the enthalpy and temperature of decomposition of the 1:1 adduct.
M. Farina, J. Chem. Soc., Chem. Commun., 1987, 1121 DOI: 10.1039/C39870001121
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