SCHEDULED MAINTENANCE
Hydroformylation of paraformaldehyde and 37% aqueous formaldehyde to give glycolaldehyde with selectivity up to ca. 90% has been carried out in acetone at 90–140 °C and 100–140 atm of carbon monoxide–hydrogen with halide-promoted Rh4(CO)12 as catalyst precursor.
M. Marchionna and G. Longoni, J. Chem. Soc., Chem. Commun., 1987, 1097 DOI: 10.1039/C39870001097
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