Issue 13, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Associative substitution reactions in 17 electron organometallic radicals: direct observation of the reaction of [(C5H5)Fe(CO)2]· with P(OMe)3 using very fast time-resolved i.r. spectroscopy

Andrew J. Dixon,   Steven J. Gravelle,   Lambertus J. van de Burgt,   Martyn Poliakoff,   James J. Turner  and  Eric Weitz  

Abstract

Time-resolved i.r. spectroscopy is used to monitor directly the formation of [(C5H5)Fe(CO)P(OMe)3]· in the reaction of P(OMe)3 with [(C5H5)Fe(CO)2]·, generated by 351 nm photolysis of [{(C5H5)Fe(CO)2}2] in n-heptane solution at room temperature; the reaction is an associative process with a bimolecular rate constant of 8.9 ± 2.0 × 108 dm3 mol–1 s–1.

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Article information

DOI
https://doi.org/10.1039/C39870001023
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1023-1025

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Associative substitution reactions in 17 electron organometallic radicals: direct observation of the reaction of [(C5H5)Fe(CO)2]· with P(OMe)3 using very fast time-resolved i.r. spectroscopy

A. J. Dixon, S. J. Gravelle, L. J. van de Burgt, M. Poliakoff, J. J. Turner and E. Weitz, J. Chem. Soc., Chem. Commun., 1987, 1023 DOI: 10.1039/C39870001023

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