The titanium(II) derivatives Ti(η6-arene)[(µ-X)2(AlX2)]2, (X = Br or I) in the parent aromatic hydrocarbon react with CO at atmospheric pressure to give thermally unstable complexes of proposed structure Ti[(η6-arene)(CO)2(µ-X)2-(AlX2)]AlX4 and with C2Ph2 to give tetra-substituted cyclobutadiene derivatives Ti(η4-C4Ph4)[(µ-X)2(AlX2)]2(X = Br)
P. Biagini, F. Calderazzo and G. Pampaloni, J. Chem. Soc., Chem. Commun., 1987, 1015 DOI: 10.1039/C39870001015
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...