SCHEDULED MAINTENANCE
The titanium(II) derivatives Ti(η6-arene)[(µ-X)2(AlX2)]2, (X = Br or I) in the parent aromatic hydrocarbon react with CO at atmospheric pressure to give thermally unstable complexes of proposed structure Ti[(η6-arene)(CO)2(µ-X)2-(AlX2)]AlX4 and with C2Ph2 to give tetra-substituted cyclobutadiene derivatives Ti(η4-C4Ph4)[(µ-X)2(AlX2)]2(X = Br)
P. Biagini, F. Calderazzo and G. Pampaloni, J. Chem. Soc., Chem. Commun., 1987, 1015 DOI: 10.1039/C39870001015
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