Issue 13, 1987

Hydrogen isotope effects in hydride transfer reactions of formaldehyde and glyoxal. An Ab initio and MNDO SCF-M.O. study

Abstract

Ab initio and MNDO calculations predict the hydroxide anion-catalysed intramolecular hydride transfer reaction of glyoxal to exhibit a larger kinetic hydrogen isotope effect than the intermolecular Cannizzaro reaction of formaldehyde.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 998-1000

Hydrogen isotope effects in hydride transfer reactions of formaldehyde and glyoxal. An Ab initio and MNDO SCF-M.O. study

I. H. Rajyaguru and H. S. Rzepa, J. Chem. Soc., Chem. Commun., 1987, 998 DOI: 10.1039/C39870000998

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